<?xml version="1.0" encoding="UTF-8"?>
<rss version="2.0"
	xmlns:content="http://purl.org/rss/1.0/modules/content/"
	xmlns:wfw="http://wellformedweb.org/CommentAPI/"
	xmlns:dc="http://purl.org/dc/elements/1.1/"
	xmlns:atom="http://www.w3.org/2005/Atom"
	xmlns:sy="http://purl.org/rss/1.0/modules/syndication/"
	xmlns:slash="http://purl.org/rss/1.0/modules/slash/"
	xmlns:georss="http://www.georss.org/georss" xmlns:geo="http://www.w3.org/2003/01/geo/wgs84_pos#" xmlns:media="http://search.yahoo.com/mrss/"
	>

<channel>
	<title>Syntheticnature</title>
	<atom:link href="http://syntheticnature.wordpress.com/feed/" rel="self" type="application/rss+xml" />
	<link>http://syntheticnature.wordpress.com</link>
	<description>Total Synthesis and general organic chemistry</description>
	<lastBuildDate>Sun, 29 Jan 2012 18:26:26 +0000</lastBuildDate>
	<language>en</language>
	<sy:updatePeriod>hourly</sy:updatePeriod>
	<sy:updateFrequency>1</sy:updateFrequency>
	<generator>http://wordpress.com/</generator>
<cloud domain='syntheticnature.wordpress.com' port='80' path='/?rsscloud=notify' registerProcedure='' protocol='http-post' />
<image>
		<url>http://s2.wp.com/i/buttonw-com.png</url>
		<title>Syntheticnature</title>
		<link>http://syntheticnature.wordpress.com</link>
	</image>
	<atom:link rel="search" type="application/opensearchdescription+xml" href="http://syntheticnature.wordpress.com/osd.xml" title="Syntheticnature" />
	<atom:link rel='hub' href='http://syntheticnature.wordpress.com/?pushpress=hub'/>
		<item>
		<title>Natural product–inspired cascade synthesis yields modulators of centrosome integrity</title>
		<link>http://syntheticnature.wordpress.com/2012/01/28/natural-product-inspired-cascade-synthesis-yields-modulators-of-centrosome-integrity/</link>
		<comments>http://syntheticnature.wordpress.com/2012/01/28/natural-product-inspired-cascade-synthesis-yields-modulators-of-centrosome-integrity/#comments</comments>
		<pubDate>Sat, 28 Jan 2012 12:57:50 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Method]]></category>
		<category><![CDATA[Biomimetic]]></category>
		<category><![CDATA[Michael]]></category>
		<category><![CDATA[Multicomponent reaction]]></category>
		<category><![CDATA[Natural products]]></category>
		<category><![CDATA[Phosphine]]></category>
		<category><![CDATA[Tandem reaction]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=967</guid>
		<description><![CDATA[Natural product–inspired cascade synthesis yields modulators of centrosome integrity Heiko Dückert, Verena Pries, Vivek Khedkar, Sascha Menninger, Hanna Bruss, Alexander W Bird, Zoltan Maliga, Andreas Brockmeyer, Petra Janning, Anthony Hyman, Stefan Grimme, Markus Schürmann, Hans Preut, Katja Hübel, Slava Ziegler, Kamal Kumar &#38; Herbert Waldmann DOI: http://dx.doi.org/10.1038/NChemBio.758 I will start this write-up with a question [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=967&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2012/01/28/natural-product-inspired-cascade-synthesis-yields-modulators-of-centrosome-integrity/feed/</wfw:commentRss>
		<slash:comments>2</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_1_25012012.png" medium="image">
			<media:title type="html">scheme_1_25012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_2_25012012.png" medium="image">
			<media:title type="html">scheme_2_25012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_3_25012012.png" medium="image">
			<media:title type="html">scheme_3_25012012</media:title>
		</media:content>
	</item>
		<item>
		<title>Total Synthesis of Carolacton, a Highly Potent Biofilm Inhibitor</title>
		<link>http://syntheticnature.wordpress.com/2012/01/05/total-synthesis-of-carolacton-a-highly-potent-biofilm-inhibitor/</link>
		<comments>http://syntheticnature.wordpress.com/2012/01/05/total-synthesis-of-carolacton-a-highly-potent-biofilm-inhibitor/#comments</comments>
		<pubDate>Thu, 05 Jan 2012 16:58:17 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Aldol reaction]]></category>
		<category><![CDATA[Macrolactonization]]></category>
		<category><![CDATA[Marshall]]></category>
		<category><![CDATA[Negishi]]></category>
		<category><![CDATA[Nozaki-Hiyama-Kishi]]></category>
		<category><![CDATA[Palladium]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=945</guid>
		<description><![CDATA[Total Synthesis of Carolacton, a Highly Potent Biofilm Inhibitor Thomas Schmidt and Andreas Kirschning DOI: http://dx.doi.org/10.1002/anie.201106762 Happy new year everybody&#8230; I start this year with a nice synthesis from my university done by a very smart student. In this paper a lot of cool metal mediated chemistry is employed which reminds me a bit of [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=945&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2012/01/05/total-synthesis-of-carolacton-a-highly-potent-biofilm-inhibitor/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_1_05012012.png" medium="image">
			<media:title type="html">scheme_1_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_2_05012012.png" medium="image">
			<media:title type="html">scheme_2_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_3_05012012.png" medium="image">
			<media:title type="html">scheme_3_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_4_05012012.png" medium="image">
			<media:title type="html">scheme_4_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_5_05012012.png" medium="image">
			<media:title type="html">scheme_5_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_6_050120121.png" medium="image">
			<media:title type="html">scheme_6_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_7_05012012.png" medium="image">
			<media:title type="html">scheme_7_05012012</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2012/01/scheme_8_050120121.png" medium="image">
			<media:title type="html">scheme_8_05012012</media:title>
		</media:content>
	</item>
		<item>
		<title>(+)-Sorangicin A: evolution of a viable synthetic strategy</title>
		<link>http://syntheticnature.wordpress.com/2011/12/11/sorangicin-a-evolution-of-a-viable-synthetic-strategy/</link>
		<comments>http://syntheticnature.wordpress.com/2011/12/11/sorangicin-a-evolution-of-a-viable-synthetic-strategy/#comments</comments>
		<pubDate>Sun, 11 Dec 2011 15:15:38 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Aldol reaction]]></category>
		<category><![CDATA[Cycloaddition]]></category>
		<category><![CDATA[Diels Alder]]></category>
		<category><![CDATA[Julia olefination]]></category>
		<category><![CDATA[Macrolactonization]]></category>
		<category><![CDATA[Palladium]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=921</guid>
		<description><![CDATA[(+)-Sorangicin A: evolution of a viable synthetic strategy Amos B. Smith III., Shuzhi Dong, Richard J. Fox, Jehrod B. Brenneman, John A. Vanecko, Tomohiro Maegawa  DOI: http://dx.doi.org/10.1016/j.tet.2011.09.035 Sorangicin A is an extremely potent antibiotic acting against Gram-positive and Gram-negative bacteria with a MIC ranging from 0.3 to 25 µg/ml, respectively. It inhibits the RNA polymerase [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=921&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/12/11/sorangicin-a-evolution-of-a-viable-synthetic-strategy/feed/</wfw:commentRss>
		<slash:comments>2</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_1_11122011.png" medium="image">
			<media:title type="html">scheme_1_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_2_111220111.png" medium="image">
			<media:title type="html">scheme_2_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_3_11122011.png" medium="image">
			<media:title type="html">scheme_3_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_4_11122011.png" medium="image">
			<media:title type="html">scheme_4_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_5_11122011.png" medium="image">
			<media:title type="html">scheme_5_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_6_11122011.png" medium="image">
			<media:title type="html">scheme_6_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_7_111220111.png" medium="image">
			<media:title type="html">scheme_7_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_8_111220111.png" medium="image">
			<media:title type="html">scheme_8_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_9_11122011.png" medium="image">
			<media:title type="html">scheme_9_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_10_11122011.png" medium="image">
			<media:title type="html">scheme_10_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_11_11122011.png" medium="image">
			<media:title type="html">scheme_11_11122011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/12/scheme_12_11122011.png" medium="image">
			<media:title type="html">scheme_12_11122011</media:title>
		</media:content>
	</item>
		<item>
		<title>Identification of an unexpected 2-oxonia[3,3]sigmatropic  rearrangement/aldol pathway in the formation of oxacyclic rings &#8211;  Total synthesis of (+)-Aspergillin PZ</title>
		<link>http://syntheticnature.wordpress.com/2011/11/24/identification-of-an-unexpected-2-oxonia33sigmatropic-rearrangementaldol-pathway-in-the-formation-of-oxacyclic-rings-total-synthesis-of-aspergillin-pz/</link>
		<comments>http://syntheticnature.wordpress.com/2011/11/24/identification-of-an-unexpected-2-oxonia33sigmatropic-rearrangementaldol-pathway-in-the-formation-of-oxacyclic-rings-total-synthesis-of-aspergillin-pz/#comments</comments>
		<pubDate>Thu, 24 Nov 2011 16:14:55 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Organic reactions]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Aldol reaction]]></category>
		<category><![CDATA[Diels Alder]]></category>
		<category><![CDATA[Rearrangement]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=910</guid>
		<description><![CDATA[Identification of an unexpected 2-oxonia[3,3]sigmatropic  rearrangement/aldol pathway in the formation of oxacyclic rings &#8211; Total synthesis of (+)-Aspergillin PZ  Stephen M. Canham, Larry E. Overman, Paul S. Tanis DOI: http://dx.doi.org/10.1016/j.tet.2011.09.079 Aspergillin PZ was isolated in 2002 by a Chinese group from a soil fungus and contains an interesting 12-oxatricyclo[6.3.1.0]dodecane ring system. Its structure is very [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=910&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/11/24/identification-of-an-unexpected-2-oxonia33sigmatropic-rearrangementaldol-pathway-in-the-formation-of-oxacyclic-rings-total-synthesis-of-aspergillin-pz/feed/</wfw:commentRss>
		<slash:comments>4</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_1_24112011.png" medium="image">
			<media:title type="html">scheme_1_24112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_2_24112011.png" medium="image">
			<media:title type="html">scheme_2_24112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_3_24112011.png" medium="image">
			<media:title type="html">scheme_3_24112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_4_24112011.png" medium="image">
			<media:title type="html">scheme_4_24112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_5_24112011.png" medium="image">
			<media:title type="html">scheme_5_24112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_6_24112011.png" medium="image">
			<media:title type="html">scheme_6_24112011</media:title>
		</media:content>
	</item>
		<item>
		<title>Total Synthesis of Tulearin C</title>
		<link>http://syntheticnature.wordpress.com/2011/11/09/total-synthesis-of-tulearin-c/</link>
		<comments>http://syntheticnature.wordpress.com/2011/11/09/total-synthesis-of-tulearin-c/#comments</comments>
		<pubDate>Wed, 09 Nov 2011 14:21:55 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[BINAP]]></category>
		<category><![CDATA[Chlorination]]></category>
		<category><![CDATA[Desymmetrization]]></category>
		<category><![CDATA[Grob fragmentation]]></category>
		<category><![CDATA[Macrolactonization]]></category>
		<category><![CDATA[Metathesis]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=894</guid>
		<description><![CDATA[Total Synthesis of Tulearin C Konrad Lehr, Ronaldo Mariz, Lucie Leseurre, Barbara Gabor, and Alois Fürstner  DOI: http://dx.doi.org/10.1002/anie.201106117 Tulearin C is at first sight a rather simple polyketide natural product. Only seven stereocenters of which only four are contiguous and none of them is quaternary. Nevertheless no useful route to this compound has been established [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=894&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/11/09/total-synthesis-of-tulearin-c/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_1_05112011.png" medium="image">
			<media:title type="html">scheme_1_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_2_05112011.png" medium="image">
			<media:title type="html">scheme_2_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_3_05112011.png" medium="image">
			<media:title type="html">scheme_3_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_4_05112011.png" medium="image">
			<media:title type="html">scheme_4_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_5_05112011.png" medium="image">
			<media:title type="html">scheme_5_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_6_05112011.png" medium="image">
			<media:title type="html">scheme_6_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_7_05112011.png" medium="image">
			<media:title type="html">scheme_7_05112011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/11/scheme_8_05112011.png" medium="image">
			<media:title type="html">scheme_8_05112011</media:title>
		</media:content>
	</item>
		<item>
		<title>Total Synthesis of (+)-Daphmanidin E</title>
		<link>http://syntheticnature.wordpress.com/2011/10/25/total-synthesis-of-daphmanidin-e/</link>
		<comments>http://syntheticnature.wordpress.com/2011/10/25/total-synthesis-of-daphmanidin-e/#comments</comments>
		<pubDate>Tue, 25 Oct 2011 14:14:07 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Claisen]]></category>
		<category><![CDATA[Heck]]></category>
		<category><![CDATA[Palladium]]></category>
		<category><![CDATA[Stereodifferentiation]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=880</guid>
		<description><![CDATA[Total Synthesis of (+)-Daphmanidin E Matthias E. Weiss and Erick M. Carreira  DOI: http://dx.doi.org/10.1002/anie.201104681 It is pretty hard to decide these days which synthesis should be reviewed. Luckily the great accomplishment of the Fukuyama group (Gelsemoxonine) has recently been reviewed on B.R.S.M so I chose the exceptional work done by the Carreira group at the [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=880&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/10/25/total-synthesis-of-daphmanidin-e/feed/</wfw:commentRss>
		<slash:comments>1</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_1_25102011.png" medium="image">
			<media:title type="html">scheme_1_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_2_25102011.png" medium="image">
			<media:title type="html">scheme_2_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_3_25102011.png" medium="image">
			<media:title type="html">scheme_3_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_4_25102011.png" medium="image">
			<media:title type="html">scheme_4_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_5_25102011.png" medium="image">
			<media:title type="html">scheme_5_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_6_25102011.png" medium="image">
			<media:title type="html">scheme_6_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_7_25102011.png" medium="image">
			<media:title type="html">scheme_7_25102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_8_25102011.png" medium="image">
			<media:title type="html">scheme_8_25102011</media:title>
		</media:content>
	</item>
		<item>
		<title>Total Synthesis of (±)-Streptonigrin: De Novo Construction of a Pentasubstituted Pyridine using Ring-Closing Metathesis</title>
		<link>http://syntheticnature.wordpress.com/2011/10/12/total-synthesis-of-%c2%b1-streptonigrin-de-novo-construction-of-a-pentasubstituted-pyridine-using-ring-closing-metathesis/</link>
		<comments>http://syntheticnature.wordpress.com/2011/10/12/total-synthesis-of-%c2%b1-streptonigrin-de-novo-construction-of-a-pentasubstituted-pyridine-using-ring-closing-metathesis/#comments</comments>
		<pubDate>Wed, 12 Oct 2011 13:39:59 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Metathesis]]></category>
		<category><![CDATA[Palladium]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=868</guid>
		<description><![CDATA[Total Synthesis of (±)-Streptonigrin: De Novo Construction of a Pentasubstituted Pyridine using Ring-Closing Metathesis Timothy J. Donohoe, Christopher R. Jones, and Luiz C. A. Barbosa DOI: http://dx.doi.org/10.1021/ja207835w Streptonigrin is a rather interesting natural product because of its axial chirality between rings C and D which was determined to be M. It contains a highly substituted quinoline [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=868&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/10/12/total-synthesis-of-%c2%b1-streptonigrin-de-novo-construction-of-a-pentasubstituted-pyridine-using-ring-closing-metathesis/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_1_12102011.png" medium="image">
			<media:title type="html">scheme_1_12102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_2_12102011.png" medium="image">
			<media:title type="html">scheme_2_12102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_3_12102011.png" medium="image">
			<media:title type="html">scheme_3_12102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_4_12102011.png" medium="image">
			<media:title type="html">scheme_4_12102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_5_12102011.png" medium="image">
			<media:title type="html">scheme_5_12102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_6_12102011.png" medium="image">
			<media:title type="html">scheme_6_12102011</media:title>
		</media:content>
	</item>
		<item>
		<title>A General Strategy for the Stereocontrolled Preparation of Diverse 8- and 9-Membered Laurencia-Type Bromoethers</title>
		<link>http://syntheticnature.wordpress.com/2011/10/02/a-general-strategy-for-the-stereocontrolled-preparation-of-diverse-8-and-9-membered-laurencia-type-bromoethers/</link>
		<comments>http://syntheticnature.wordpress.com/2011/10/02/a-general-strategy-for-the-stereocontrolled-preparation-of-diverse-8-and-9-membered-laurencia-type-bromoethers/#comments</comments>
		<pubDate>Sun, 02 Oct 2011 12:04:51 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Aldol reaction]]></category>
		<category><![CDATA[Biomimetic]]></category>
		<category><![CDATA[Claisen]]></category>
		<category><![CDATA[Natural products]]></category>
		<category><![CDATA[Organocatalysis]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=847</guid>
		<description><![CDATA[A General Strategy for the Stereocontrolled Preparation of Diverse 8- and 9-Membered Laurencia-Type Bromoethers Scott A. Snyder, Daniel S. Treitler, Alexandria P. Brucks, and Wesley Sattler DOI: http://dx.doi.org/10.1021/ja2069449 DOi: http://dx.doi.org/10.1002/anie.200903834 This time some cool methodology from the Snyder group involving the use of a recently reported new reagent: BDSB. It is formed by the reaction [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=847&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/10/02/a-general-strategy-for-the-stereocontrolled-preparation-of-diverse-8-and-9-membered-laurencia-type-bromoethers/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_1_02102011.png" medium="image">
			<media:title type="html">scheme_1_02102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_2_031020111.png" medium="image">
			<media:title type="html">scheme_2_03102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_3_03102011.png" medium="image">
			<media:title type="html">scheme_3_03102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_4_03102011.png" medium="image">
			<media:title type="html">scheme_4_03102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_5_02102011.png" medium="image">
			<media:title type="html">scheme_5_02102011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/10/scheme_6_02102011.png" medium="image">
			<media:title type="html">scheme_6_02102011</media:title>
		</media:content>
	</item>
		<item>
		<title>A Concise Total Synthesis of (-)-Maoecrystal Z</title>
		<link>http://syntheticnature.wordpress.com/2011/09/05/a-concise-total-synthesis-of-maoecrystal-z/</link>
		<comments>http://syntheticnature.wordpress.com/2011/09/05/a-concise-total-synthesis-of-maoecrystal-z/#comments</comments>
		<pubDate>Mon, 05 Sep 2011 09:02:33 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Aldol reaction]]></category>
		<category><![CDATA[Resolution]]></category>
		<category><![CDATA[Samarium iodide]]></category>
		<category><![CDATA[SET]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=832</guid>
		<description><![CDATA[A Concise Total Synthesis of (-)-Maoecrystal Z Jacob Y. Cha, John T. S. Yeoman, and Sarah E. Reisman DOI: http://dx.doi.org/10.1021/ja2073356 Recently I stumbled onto this excellent paper from the Reisman group. While reading the paper I wondered if I ever reviewed one of their total syntheses because of the very appealing tactics employed by the [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=832&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/09/05/a-concise-total-synthesis-of-maoecrystal-z/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_1_03092011.png" medium="image">
			<media:title type="html">scheme_1_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_2_03092011.png" medium="image">
			<media:title type="html">scheme_2_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_3_03092011.png" medium="image">
			<media:title type="html">scheme_3_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_4_03092011.png" medium="image">
			<media:title type="html">scheme_4_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_5_03092011.png" medium="image">
			<media:title type="html">scheme_5_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_6_03092011.png" medium="image">
			<media:title type="html">scheme_6_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_7_03092011.png" medium="image">
			<media:title type="html">scheme_7_03092011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/09/scheme_8_05092011.png" medium="image">
			<media:title type="html">scheme_8_05092011</media:title>
		</media:content>
	</item>
		<item>
		<title>Synthesis of Undecachlorosulfolipid A: Re-evaluation of the Nominal Structure</title>
		<link>http://syntheticnature.wordpress.com/2011/08/20/synthesis-of-undecachlorosulfolipid-a-re-evaluation-of-the-nominal-structure/</link>
		<comments>http://syntheticnature.wordpress.com/2011/08/20/synthesis-of-undecachlorosulfolipid-a-re-evaluation-of-the-nominal-structure/#comments</comments>
		<pubDate>Sat, 20 Aug 2011 08:10:53 +0000</pubDate>
		<dc:creator>syntheticnature</dc:creator>
				<category><![CDATA[Synthetic Methods]]></category>
		<category><![CDATA[Total Synthesis]]></category>
		<category><![CDATA[Asymmetric Halogenation]]></category>
		<category><![CDATA[Chlorination]]></category>
		<category><![CDATA[Sharpless]]></category>

		<guid isPermaLink="false">http://syntheticnature.wordpress.com/?p=818</guid>
		<description><![CDATA[Synthesis of Undecachlorosulfolipid A: Re-evaluation of the Nominal Structure Christian Nilewski, Nicholas R. Deprez, Thomas C. Fessard, Dong Bo Li, Roger W. Geisser, and Erick M. Carreira  DOI: http://dx.doi.org/10.1002/anie.201102521 This time I will present to you a real beasty of a molecule. It belongs to the class of the chlorosulfolipids which gained some synthetic interest [...]<img alt="" border="0" src="http://stats.wordpress.com/b.gif?host=syntheticnature.wordpress.com&amp;blog=5872162&amp;post=818&amp;subd=syntheticnature&amp;ref=&amp;feed=1" width="1" height="1" />]]></description>
		<wfw:commentRss>http://syntheticnature.wordpress.com/2011/08/20/synthesis-of-undecachlorosulfolipid-a-re-evaluation-of-the-nominal-structure/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
	
		<media:content url="http://0.gravatar.com/avatar/03aa7ba2b752d7836154b2dd264d191f?s=96&#38;d=identicon" medium="image">
			<media:title type="html">syntheticnature</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_1_09082011.png" medium="image">
			<media:title type="html">scheme_1_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_2_09082011.png" medium="image">
			<media:title type="html">scheme_2_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_3_09082011.png" medium="image">
			<media:title type="html">scheme_3_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_4_09082011.png" medium="image">
			<media:title type="html">scheme_4_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_5_09082011.png" medium="image">
			<media:title type="html">scheme_5_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_6_09082011.png" medium="image">
			<media:title type="html">scheme_6_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_7_09082011.png" medium="image">
			<media:title type="html">scheme_7_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_8_09082011.png" medium="image">
			<media:title type="html">scheme_8_09082011</media:title>
		</media:content>

		<media:content url="http://syntheticnature.files.wordpress.com/2011/08/scheme_9_09082011.png" medium="image">
			<media:title type="html">scheme_9_09082011</media:title>
		</media:content>
	</item>
	</channel>
</rss>
